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Doctor Austin and Doug Saftey's Time-Tastical Time Tale, Risk Assessment

Risk Assessments for Time-Tastical Time Tale

Carbon dioxide risk assessments

Peg Time Perception Experiment


No risks associated with this experiment.


Liquid Nitrogen Experiments

Liquid nitrogen risk assessments



Time-Tastical Productions Risk Assessment



Diamond Burning


Title: Diamond Burning

Description: This demo involves the heating and burning of a diamond in Liquid Oxygen













HazardRisksExisting Control MeasuresRisk Rating 
Calculated using the table at the bottom of the page.
Additional Controls to reduce risk to as low as reasonably practicable, (ALARP)Action required by
DateFinal Risk Rating
Liquid Nitrogen is used in the making of Liquid Oxygen.
See the Liquid Nitrogen Risk Assessment.
See the Liquid Nitrogen Risk Assessment.See the Liquid Nitrogen Risk Assessment.See the Liquid Nitrogen Risk Assessment.See the Liquid Nitrogen Risk Assessment.See the Liquid Nitrogen Risk Assessment.See the Liquid Nitrogen Risk Assessment.
Liquid Oxygen makes reactions hugely more reactive.
Fire and explosive reaction. Fuels become much more flammable and flammables explosive.Only small amounts, up to 50ml stored in one place. Store separately from flammables.
Likelihood: M  
Severity: M
Risk Rating: H
Goggles worn at all times. Work on dense non-porous surface and use non-porous utensils. Allow spillages to evaporate. Use small quantities at a time, up to 10ml. It should not be stored overnight but allowed to evaporate away in a safe manner.
Presenter
Ongoing
Likelihood: L
Severity: L
Risk Rating: L
Liquid Oxygen, -183C.
Cold injury - can cause serious cold burns and frost bite.Only small amounts available.
Likelihood: M  
Severity: M
Risk Rating: H
Gloves and goggles should be worn at all times while transporting and handling liquid oxygen.
Presenter
Ongoing
Likelihood: L
Severity: L
Risk Rating: L
Liquid Oxygen can rapidly evaporate and as a gas take up a volume 1000Xs original.This can cause containers to explode.Use specially designed containers.
Likelihood: M  
Severity: H
Risk Rating: H
If not in a specialised container then a container should only be restricted by a loose lid.
PresenterOngoingLikelihood: L
Severity: L
Risk Rating: L
Gas burner to heat diamond. Burns to the presenter.
Follow instructions on gas burner.
Likelihood: M  
Severity: M
Risk Rating: H
Goggles worn at all times. Use tripod or tweezers to hold the diamond.
 Allow burner to cool in a safe place.  Heat protective gloves should be available.
PresenterOngoingLikelihood: L
Severity: L
Risk Rating: L
Gas burner to heat diamond.Fire
Fire extinguishers should be available at location.
Likelihood: M  
Severity: H
Risk Rating: H
Remove flammable materials from immediate vicinity before using. Do not leave hot burner near possible sources of fuel.PresenterOngoingLikelihood: L
Severity: L
Risk Rating: L





Spinning Toilet - Time Dilation Experiment


This is a new demo, where Austin is spun around in the toilet. The risk assessment will follow shortly but will be low risk.


Tesla Coil



Title:  Small Tesla Coil

Description: This concerns the general operation of the Tesla Coil and Flash Cotton Experiment.


RisksExisting Control Measures
Risk Rating 
(Calculated using the table at the bottom of the page)
Additional Controls to reduce risk to as low as reasonably practicable, (ALARP)Action required by
DateFinal Risk Rating
Electric shockAlthough this is a high voltage the current is low and unlikely to cause serious injury. 
Likelihood: M
Severity: L
Risk Rating: L

The audience must be more than 2 meters form the coil.


The immediate 1 meter area around the coils must be clear.


The lightning conductor, cable and connector should be inspected for damage.

Presenter

Ongoing
Likelihood: L 
Severity: L 
Risk Rating: L

Accidental activation of Tesla Coil near operator resulting in electric shock.


Although this is a high voltage the current is low and unlikely to cause serious injury.
Likelihood: M
Severity: L   
Risk Rating: L

Power cable and activation button must be disconnected from Tesla Coil at all times when not in active use.

Presenter

OngoingLikelihood: L 
Severity: L 
Risk Rating: L
The Tesla coil base contains high voltages and currents. Electric shock could result in injury or death.

A fault could cause this high voltage and current to pass through to the secondary coil.
The base is completely insulated.
Likelihood: M
Severity: H
Risk Rating: H
The operator should inspect the casing and components for damage. Do not use if damaged.

The 'lightning'   conductor must always be between the operator and the coil when the power lead is in.

Assume that the coil is live when the power lead is attached.

The coil should never be touched during operation.
Presenter
OngoingLikelihood: L
Severity: H
Risk Rating: M
 
 

 




Hydrogen Rocket

Title:  Hydrogen Rocket 

Description: This demo involves exploding hydrogen in a plastic bottle launching it like a rocket.

HazardRisksExisting Control MeasuresRisk Rating 
Calculated using the table at the bottom of the page.
Additional Controls to reduce risk to as low as reasonably practicable, (ALARP)Action requiredBy & dateFinal Risk Rating
Exploding hydrogen launching plastic drinks bottle. 

Explosive reaction near presenter and audience

  • Burns from fireball

  • Impact from blast

  • Damage to ear drums

  • Eye injury

None
Likelihood: M  
Severity: M
Risk Rating: H

Goggles worn at all times.

Ear defenders to be worn, audience warned of loud explosion

Area cleared of fragile material

Presenter

Ongoing
Likelihood: L 
Severity: L 
Risk Rating: L

Rocket travelling v. fast

Impact injury to audience or presenter

Small amount of hydrogen, 2l bottle,  to reduce risk of too big an explosion.Likelihood: M  
Severity: M
Risk Rating: H

Rocket always fired along trajectory directed away from or parallel to audience, and away from presenter

Presenter

OngoingLikelihood: L 
Severity: L 
Risk Rating: L

Rocket igniting and burning as it flies

fire hazard to stage area and audience

Correct mixture of H2 and air (50:50) to ensure correct ignitionLikelihood: L
Severity: H
Risk Rating: M

Any flammable materials removed from area of launch and flight

Presenter

OngoingLikelihood: L 
Severity: L 
Risk Rating: L




Making Hydrogen (H2) gas from Caustic Soda (sodium hydroxide - NaOH)

Making Hydrogen rocket using Caustic Soda and Aluminium Foil


The aim of this experiment is to make and launch a Hydrogen fueled rocket.
 
We will begin by making hydrogen, always do so in a well ventilated area.

2Al(s) + 2NaOH(aq) + 6H2O(l) ---> 2Na(Al(OH)4)(aq) + 3H2(g) 
  
  1. Make 3 - 5 small balls of aluminium foil and set them on the side.
  2. Ensure that you have the necessary equipment as detailed below to hand. Be extra sure to ensure you have access to running water and a container with cold water in case you need it quickly.
  3. Put on your goggles & gloves.
  4. Quarter fill the Büchner flask (with hose attached) with water and add a small amount of caustic soda. Take care to add caustic soda slowly as it causes an exothermic reaction.
  5. Pop in the foil balls, this will make the mixture fizz and cause steam to rise - take care not to allow the flask to get too warm, place in cold water container if this does happen
  6. Place the end of the hose on the flask beneath the water level of the basin inside another plastic bottle half full with water (this allows a hydrogren / air mix giving some oxygen to facilitate a rapid explosion)
  7. Place the stopper on the flask this will fill the water filled bottle with gas
  8. As soon as it is full remove the stopper
  9. Whilst holding the now gas filled bottle upside down put a lid on it to stop the gas escaping - you hydrogen rocket has now be fueled & is ready for blast off!
  10. Don't run off and launch it now, MAKE SURE you follow the disposal instructions below for safe clean up from this experiment!

Disposal

Small amounts of dilute sodium hydroxide can be flushed down a sink with a large quantity of water, unless local rules prohibit this. Larger amounts should be neutralised before disposal.

Equipment List

  • Büchner flask
  • Stopper
  • Hose
  • Water
  • Bucket
  • Basin
  • Aluminium foil
  • Safety gloves
  • Safety goggles
  • Measuring spoon
  • Bottle
  • Running water
  • Eye wash facilities
  • Well ventilated area
  • Sparker
  • Launch stand
  • Blast shield
  • Ear defenders


 Risk assessments

Click the links for the the associated risk assessments:
  • Making hydrogen
  • Hydrogen rocket



This risk assessment concerns the making of hydrogen, see experiments. The experiment concerns the addition of aluminium foil to caustic soda to produce the hydrogen gas. This guidance is primarily applicable to small quantities of chemicals and thus the general danger from large amounts of hydrogen gas is low. The main dangers come from the corrosive nature of caustic soda. Caustic soda is a common name for sodium hydroxide.
 

Hazard: Corrosive caustic soda 

Caustic soda is a strong alkali, its solid and solutions are corrosive and can cause chemical burns.
 

Risk: chemical burns

If it comes into contact with the skin it can cause skin damage - chemical burn. 
  • Existing Control Measures: The bottles containing the hydrogen peroxide have labels detaining the dangers and precautions
  • Risk Rating (Calculated using the table at the bottom of the page): Likely x Notable-injury = High
  • Additional Controls to reduce risk to as low as reasonably practicable, (ALARP):
    1. Wear rubber gloves
    2. Have water available to flood skin
  • Action required by: Experimenter
  • Date: Ongoing
  • Final Risk Rating: Likely x Minor-injury = Medium

Risk: eye damage

Contact with the eyes can cause serious long-term damage.
  • Existing Control Measures: The bottles containing the hydrogen peroxide have labels detaining the dangers and precautions.
  • Risk Rating (Calculated using the table at the bottom of the page): Rare x Serious-injury = High
  • Additional Controls to reduce risk to as low as reasonably practicable, (ALARP):
    1. Wear goggles
    2. Have water available at hand to flood eyes
  • Action required by: Experimenter
  • Date: Ongoing
  • Final Risk Rating: Unlikely x Notable-injury = Medium

Hazard: Rapid exothermic chemical reaction


The experiment concerns the addition of aluminium foil to caustic soda solution to produce hydrogen gas. Heat is released when sodium hydroxide is dissolved in water and even more so when aluminium is added.

Risk: Splashing chemicals

The rapid chemical reaction can cause splashes of the chemicals involved. The primary danger comes again from the hydrogen peroxide, see the precautions above.

  • Existing Control Measures: The bottles containing the hydrogen peroxide have labels detaining the dangers and precautions
  • Risk Rating (Calculated using the table at the bottom of the page): Likely x Serious-injury = High
  • Additional Controls to reduce risk to as low as reasonably practicable, (ALARP):
    1. Add caustic soda to water.
    2. Always add aluminum to the caustic soda.
    3. Wear rubber gloves
    4. Have water available to flood skin
    5. Add aluminum foil slowly
    6. Have water at hand to cool and dilute the reaction
  • Action required by: Experimenter
  • Date: Ongoing
  • Final Risk Rating: Likely x Notable-injury = Medium


Hydrogen Peroxide (H2O2)



Hazard: Hydrogen peroxide oxidizing

Hydrogen peroxide is strongly oxidizing. Which means that it reacts strongly, taking electrons from the other substances involved the chemical reaction.

Risk: skin damage

If it comes into contact with the skin it can cause skin damage - chemical burn. 
  • Existing Control Measures: The bottles containing the hydrogen peroxide have labels detaining the dangers and precautions
  • Risk Rating (Calculated using the table at the bottom of the page): Likely x Notable-injury = High
  • Additional Controls to reduce risk to as low as reasonably practicable, (ALARP):
  1. Wear rubber gloves
  2. Have water available to flood skin
  • Action required by: Experimenter
  • Date: Ongoing
  • Final Risk Rating: Likely x Minor-injury = Medium

Risk: eye damage

  • Existing Control Measures: The bottles containing the hydrogen peroxide have labels detaining the dangers and precautions.
  • Risk Rating (Calculated using the table at the bottom of the page): Rare x Serious-injury = High
  • Additional Controls to reduce risk to as low as reasonably practicable, (ALARP):
  1. Wear goggles
  2. Have water available at hand to flood eyes
  • Action required by: Experimenter
  • Date: Ongoing
  • Final Risk Rating: Unlikely x Notable-injury = Medium











CO2 suppliers
Messers UK - best for alternative venue
BOC Gasses - 0800 111 333



CO2 Cloud Title:  Indoor cloud.

Description:  This experiment consists of solid carbon dioxide pellets being added to hot water, producing a mist of condensed water droplets. 


HazardRisksExisting Control Measures
Risk Rating 
(Calculated using the table at the bottom of the page)
Additional Controls to reduce risk to as low as reasonably practicable, (ALARP)Action required by
DateFinal Risk Rating

Carbon dioxide gas 

Carbon dioxide displacing air causing asphyxiation.  
Warning labels on product.
Likelihood: L
Severity: H
Risk Rating: H

Store and use in large well ventilated areas.


Transport in a separate compartment to the driver or passengers.


Presenter

Ongoing
Likelihood: L
Severity: M
Risk Rating: M

Carbon dioxide sublimating at −78°C

Risk of cold injury.


Warning labels on product.

Likelihood: M
Severity: L   
Risk Rating: L
Use protective gloves and goggles.

Store in insulated containers.

Presenter

OngoingLikelihood: M
Severity: L 
Risk Rating: L
Expanding sublimating carbon dioxide.  
Expanding gas can can explode containers with fixed lids and no vent.
Delivered in plastic bags.
Likelihood: M
Severity: H
Risk Rating: H
Always store in containers with loose lid.
Presenter
OngoingLikelihood: L
Severity: L 
Risk Rating: L
Hot water.
When the carbon dioxide is added to the hot water, the expanding gas can cause water to be splashed out, causing burns.
Use hot but not boiling water. 
Likelihood: M
Severity: M
Risk Rating: H
Do not fill the container more than half full of water.
Presenter
Ongoing
Likelihood: L
Severity: L 
Risk Rating: L
Water liquid splashed onto on the ground.
Slip hazard
Common sense 
Likelihood: M
Severity: M
Risk Rating: H
Do not fill the container more than half full of water.

Wipe up significant spillages that could cause a slip.
Presenter
OngoingLikelihood: L
Severity: M
Risk Rating: L


Hazard information
Cold burns, frostbite and hypothermia from the intense cold

Liquid nitrogen poses special problems due to its extreme low temperature (-196 oC). Contact with the liquid, or even cold vapour or gas, can produce damage to the skin similar to heat burns. Wear the eye protection and cryogloves provided (see Handling / Preparation,  below)


  • Asphyxiation in oxygen deficient atmospheres

Liquid nitrogen is an asphyxiant. When the liquid vaporises, a large volume of gas is generated. This presents an asphyxiation hazard the magnitude of which is dependent on the volume of the liquid nitrogen flask in relation to that of the room.

  • Over-pressurisation from the large volume expansion of the liquid

The ratio of the volume of gas to liquid, measured at 15°C and one atmosphere, is 682. Confinement of the gas can result in a potentially explosive situation (see flask venting and type below).

  • Fire in oxygen enriched atmospheres

Be aware that oxygen enrichment and a fire hazard can result from the condensation of oxygen (boiling point -183C) from the air onto piping cooled by liquid nitrogen (boiling point -196°C). This risk can be limited by restricting the volume of liquid nitrogen used.


PROCEDURES

Storage/transportation

  • Liquid nitrogen should be stored in a flask that has been designed specifically for containing cryogenic liquids (6 litre stainless steel Dewar or 25 litre egg) in a well ventilated room.

  • Never attempt to prevent vapours from escaping from storage containers. Since they are not at thermal equilibrium, vapour is produced as the liquid boils and, if not vented to the atmosphere, could produce excessive pressures resulting in the container rupturing - possibly explosively.

  • The practice of using domestic, or outdoor activity, type flasks is dangerous because the stoppers on these flasks can form a seal at the neck.

  • Transport only in the 25 litre egg in a van that has front and rear compartments for personnel and 'goods', each vented separately to the outside air. The egg should be securely fixed to prevent movement. It is a statutory requirement that the driver is aware of what he or she is transporting and the flask cannot become overpressurized.

  • The 25 litre egg of liquid nitrogen should never be carried in a lift (elevator) alongside people, because of the remote possibility that the Dewar containing the liquid will go "soft" (i.e. lose the vacuum in the Dewar flask) and lead to sudden and rapid generation of vapour.

  • The 25 litre egg must be carried on the special trolley provided or carried by two people. The route into the demonstration site must be reconnoitred for specific risks in manual handling (see below). Ensure there is no potential for an accident with pupils in the corridors or playground. Where 'team' handling has to be used, do not involve school staff or pupils. Only specifically trained personnel are to handle the liquid nitrogen container. It is acceptable, if necessary, to prop open smoke stop doors temporarily since the avoidance of manual handling difficulties will outweigh the short term fire risks. Ensure any props are removed immediately.


    Handling / Preparation

     

  • Work in a well ventilated area of adequate volume and ensure that emergency exits are always clear.

  • Eye protection and thermal gloves must be worn whenever handling liquid nitrogen.

  • Care should be taken when using liquid nitrogen not to spill the liquid on clothing, since this can easily become saturated with the liquid and then hold the liquid next to the skin for a significant period of time, leading to serious burns. Wear loose-fitting thermal gloves, eye protection (goggles or face-shield), and trousers over closed shoes (slip-ons being preferable to lace-ups). Be extremely cautious carrying the liquid nitrogen into the school. Plan the route in to the demonstration area and the time of entry (see also "Storage/Transportation" and "Setting-up").

  • Never leave the Dewar unattended and always keep the audience at least 2-3 m away. Ensure that the Dewar is placed on a stable, steady table. When the audience are entering and leaving, stand between them and the table so that there is no danger of the Dewar being knocked over.

Disposal

  • Do not attempt to dispose of residual waste or unused quantities. Return in the container to an authorised distributor for proper disposal.

Spillage

  • Evacuate all personnel from the affected area.

Remedial Measures

Cold Burns - BOC advise that the aim of treatment is to raise the temperature of the affected part slowly back to normal.

For minor exposures:

  1. Move the victim to a comfortable room if possible.

  2. Ensure that clothing is loose to provide unrestricted circulation. Do not remove clothing that is stuck to the body until thawed thoroughly.

  3. Place affected part in TEPID WATER or run TEPID WATER over for half an hour until the skin changes from pale yellow through blue to pink or red. Do not use hot water or any other form of direct heat.

  4. Cover the affected part with a bulky, dry, sterile dressing.

  5. Send the victim to a hospital casualty department.

Asphyxiation – In case of severe drowsiness or asphyxiation open windows and then remove patient to an area with uncomtaminated air. Keep warm and place in the recovery position. A trained First Aider may be needed to apply CPR as necessary.


Setting-up

  • Again, remember the need to plan your route into the demonstration area and the timing of your entry (see above). Ensure that it is safe to carry in the equipment. If you enter during breaktime, is there potential that pupils at play or moving in corridors could be a hazard?

  • Set up your demonstration table so that it doesn’t obstruct any fire exits or thoroughfares and is in a position in the room that the audience can easily enter and exit without coming into contact with your equipment.

  • Take control of the audience as they come into the room, standing where you want the first row to sit (approx. 3 m from the demonstration table).

  • Eye protection and cryogenic gloves must be worn at all times when handling and demonstrating with liquid nitrogen. Ensure eye protection is cleaned before use.

  • All volunteers must wear eye protection.

  • If performing the demonstration in a classroom or similar sized room only put 3 l of liquid nitrogen in the Dewar. The risk being minimised by reducing the volume of liquid nitrogen which could be subject to catastrophic spillage.